La. Admin. Code tit. 33 § IX-7107

Current through Register Vol. 50, No. 9, September 20, 2024

Section IX-7107 - Appendix D-Permit Application Testing Requirements (LAC 33:IX.2501)

Table I.
Testing Requirements for Organic Toxic Pollutants by Industrial Category for Existing Dischargers
GC/MS Fraction⁽¹⁾
Industrial Category	Volatile	Acid	Base/Neutral	Pesticides
Adhesives and Sealants	*	*	*
Aluminum Forming	*	*	*
Auto and Other Laundries	*	*	*	*
Battery Manufacturing	*	*
Coal Mining	*	*	*	*
Coil Coating	*	*	*
Copper Forming	*	*	*
Electric and Electronic Components	*	*	*	*
Electroplating	*	*	*
Explosives Manufacturing	*	*
Foundries	*	*	*
Gum and Wood Chemicals	*	*	*	*
Inorganic Chemicals Manufacturing	*	*	*
Iron and Steel Manufacturing	*	*	*
Leather Tanning and Finishing	*	*	*	*
Mechanical Products Manufacturing	*	*	*
Nonferrous Metals Manufacturing	*	*	*	*
Ore Mining	*	*	*	*
Organic Chemicals Manufacturing	*	*	*	*
Paint and Ink Formulation	*	*	*	*
Pesticides	*	*	*	*
Petroleum Refining	*	*	*	*
Pharmaceutical Preparations	*	*	*
Photographic Equipment and Supplies	*	*	*	*
Plastic and Synthetic Materials Manufacturing	*	*	*	*
Plastic Processing	*
Porcelain Enameling	*	*	*
Printing and Publishing	*	*	*	*
Pulp and Paper Mills	*	*	*	*
Rubber Processing	*	*	*
Soap and Detergent Manufacturing	*	*	*
Steam Electric Power Plants	*	*	*
Textile Mills	*	*	*	*
Timber Products Processing	*	*	*	*

(1) The toxic pollutants in each fraction are listed in Table II.

* Testing required.

Table II
Organic Toxic Pollutants in Each of Four Fractions in Analysis by Gas Chromatography/Mass Spectroscopy (GS/MS)
Volatiles
1V	Acrolein
2V	Acrylonitrile
3V	Benzene
5V	Bromoform
6V	Carbon tetrachloride
7V	Chlorobenzene
8V	Chlorodibromomethane
9V	Chloroethane
10V	2-chloroethyl vinyl ether
11V	Chloroform
12V	Dichlorobromomethane
14V	1,1-dichloroethane
15V	1,2-dichloroethane
16V	1,1-dichloroethylene
17V	1,2-dichloropropane
18V	1,3-dichloropropylene
19V	Ethylbenezene
20V	Methyl bromide
21V	Methyl chloride
22V	Methylene chloride
23V	1,1,2,2-tetrachloroethane
24V	Tetrachloroethylene
25V	Toluene
26V	1,2-trans-dichloroethylene
27V	1,1,1-trichloroethane
28V	1,1,2-trichloroethane
29V	Trichloroethylene
31V	Vinyl chloride
Acid Compounds
1A	2-chlorophenol
2A	2,4-dichlorophenol
3A	2,4-dimethylphenol
4A	4,6-dinitro-o-cresol
5A	2,4-dinitrophenol
6A	2-nitrophenol
7A	4-nitrophenol
8A	p-chloro-m-cresol
9A	Pentachlorophenol
10A	Phenol
11A	2,4,6-trichlorophenol
Pesticides
1P	Aldrin
2P	Alpha-BHC
3P	Beta-BHC
4P	Gamma-BHC
5P	Delta-BHC
6P	Chlordane
7P	4,4'-DDT
8P	4,4'-DDE
9P	4,4'-DDD
10P	Dieldrin
11P	Alpha-endosulfan
12P	Beta-endosulfan
13P	Endosulfan sulfate
14P	Endrin
15P	Endrin aldehyde
16P	Heptachlor
17P	Heptachlor epoxide
18P	PCB-1242
19P	PCB-1254
20P	PCB-1221
21P	PCB-1232
22P	PCB-1248
23P	PCB-1260
24P	PCB-1016
25P	Toxaphene
Base/Neutral Compounds
1B	Acenaphthene
2B	Acenaphthylene
3B	Anthracene
4B	Benzidine
5B	Benzo(a)anthracene
6B	Benzo(a)pyrene
7B	3,4-benzofluoranthene
8B	Benzo(ghi)perylene
9B	Benzo(k)fluoranthene
10B	Bis(2-chloroethoxy)methane
11B	Bis(2-chloroethyl)ether
12B	Bis(2-chloroisopropyl)ether
13B	Bis(2-ethylhexyl)phthalate
14B	4-bromophenyl phenyl ether
15B	Butylbenzyl phthalate
16B	2-chloronaphthalene
17B	4-chlorophenyl phenyl ether
18B	Chrysene
19B	Dibenzo(a,h)anthracene
20B	1,2-dichlorobenzene
21B	1,3-dichlorobenzene
22B	1,4-dichlorobenzene
23B	3,3'-dichlorobenzidine
24B	Diethyl phthalate
25B	Dimethyl phthalate
26B	Di-n-butyl phthalate
27B	2,4-dinitrotoluene
28B	2,6-dinitrotoluene
29B	Di-n-octyl phthalate
30B	1,2-diphenylhydrazine (as azobenzene)
31B	Fluoranthene
32B	Fluorene
33B	Hexachlorobenzene
34B	Hexachlorobutadiene
35B	Hexachlorocyclopentadiene
36B	Hexachloroethane
37B	Indeno (1,2,3-cd)pyrene
38B	Isophorone
39B	Naphthalene
40B	Nitrobenzene
41B	N-nitrosodimethylamine
42B	N-nitrosodi-n-propylamine
43B	N-nitrosodiphenylamine
44B	Phenanthrene
45B	Pyrene
46B	1,2,4-trichlorobenzene

Table III

Other Toxic Pollutants (Metals and Cyanide) and Total Phenols

Antimony, Total

Arsenic, Total

Beryllium, Total

Cadmium, Total

Chromium, Total

Copper, Total

Lead, Total

Mercury, Total

Nickel, Total

Selenium, Total

Silver, Total

Thallium, Total

Zinc, Total

Cyanide, Total

Phenols, Total

Table IV

Conventional and Nonconventional Pollutants

Required to be Tested by Existing Dischargers if Expected to be Present

Bromide

Chlorine, Total Residual

Color

Fecal Coliform

Fluoride

Nitrate-Nitrite

Nitrogen, Total Organic

Oil and Grease

Phosphorous, Total

Radioactivity

Sulfate

Sulfide

Sulfite

Surfactants

Aluminum, Total

Barium, Total

Boron, Total

Cobalt, Total

Iron, Total

Magnesium, Total

Molybdenum, Total

Manganese, Total

Tin, Total

Titanium, Total

Table V

Toxic Pollutants and Hazardous Substances

Required to be Identified by Existing Dischargers if Expected to be Present

Toxic Pollutants

Asbestos

Hazardous Substances

Acetaldehyde

Allyl alcohol

Allyl chloride

Amyl acetate

Aniline

Benzonitrile

Benzyl chloride

Butyl acetate

Butylamine

Captan

Carbaryl

Carbofuran

Carbon disulfide

Chlorpyrifos

Coumaphos

Cresol

Crotonaldehyde

Cyclohexane

2,4-D (2,4-Dichlorophenoxy acetic acid)

Diazinon

Dicamba

Dichlobenil

Dichlone

2,2-Dichloropropionic acid

Dichlorvos

Diethyl amine

Dimethyl amine

Dinitrobenzene

Diquat

Disulfoton

Diuron

Epichlorohydrin

Ethion

Ethylene diamine

Ethylene dibromide

Formaldehyde

Furfural

Guthion

Isoprene

Isopropanolamine Dodecylbenzenesulfonate

Kelthane

Kepone

Malathion

Mercaptodimethur

Methoxychlor

Methyl mercaptan

Methyl methacrylate

Methyl parathion

Mevinphos

Mexacarbate

Monoethyl amine

Monomethyl amine

Naled

Napthenic acid

Nitrotoluene

Parathion

Phenolsulfanate

Phosgene

Propargite

Propylene oxide

Pyrethrins

Quinoline

Resorcinol

Strontium

Strychnine

Styrene

2,4,5-T (2,4,5-Trichlorophenoxy acetic acid)

TDE (Tetrachlorodiphenylethane)

2,4,5-TP[2- (2,4,5-Trichlorophenoxy) propanoic acid]

Trichlorfon

Triethanolamine Dodecylbenzenesulfonate

Triethylamine

Trimethylamine

Uranium

Vanadium

Vinyl Acetate

Xylene

Xylenol

Zirconium

[Note 1: The Environmental Protection Agency has suspended the requirements of 40 CFR 122.21(g)(7)(ii)(A) and Table I of Appendix D (LAC 33:IX.2501.G.7.b.i and LAC 33:IX.7107.Appendix D.Table I) as they apply to certain industrial categories. The suspensions are as follows.

a. At 46 FR 2046, January 8, 1981, the Environmental Protection Agency suspended until further notice 40 CFR 122.21(g)(7)(ii)(A) (LAC 33:IX.2501.G.7.b.i) as it applies to coal mines.

b. At 46 FR 22585, April 20, 1981, the Environmental Protection Agency suspended until further notice 40 CFR 122.21(g)(7)(ii)(A) (LAC 33:IX.2501.G.7.b.i) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for all four organic fractions in the Greige Mills Subcategory of the Textile Mills industry (Subpart C-Low water use processing of 40 CFR Part 410), and testing and reporting for the pesticide fraction in all other subcategories of this industrial category.

2. Testing and reporting for the volatile, base/neutral and pesticide fractions in the Base and Precious Metals Subcategory of the Ore Mining and Dressing industry (Subpart B of 40 CFR Part 440), and testing and reporting for all four fractions in all other subcategories of this industrial category.

3. Testing and reporting for all four GC/MS fractions in the Porcelain Enameling industry.

c. At 46 FR 35090, July 1, 1981, the Environmental Protection Agency suspended until further notice 40 CFR 122.21(g)(7)(ii)(A) (LAC 33:IX.2501.G.7.b.i) and the corresponding portions of Item V-C of the NPDES application Form 2c as they apply to:

1. Testing and reporting for the pesticide fraction in the Tall Oil Rosin Subcategory (Subpart D) and Rosin-Based Derivatives Subcategory (Subpart F) of the Gum and Wood Chemicals industry ( 40 CFR Part 454), and testing and reporting for the pesticide and base/neutral fractions in all other subcategories of this industrial category.

2. Testing and reporting for the pesticide fraction in the Leather Tanning and Finishing, Paint and Ink Formulation, and Photographic Supplies industrial categories.

3. Testing and reporting for the acid, base/neutral and pesticide fractions in the Petroleum Refining industrial category.

4. Testing and reporting for the pesticide fraction in the Papergrade Sulfite subcategories (Subparts J and U) of the Pulp and Paper industry ( 40 CFR Part 430 ); testing and reporting for the base/neutral and pesticide fractions in the following subcategories: Deink (Subpart Q), Dissolving Kraft (Subpart F), and Paperboard from Waste Paper (Subpart E); testing and reporting for the volatile, base/neutral and pesticide fractions in the following subcategories: BCT Bleached Kraft (Subpart H), Semi-Chemical (Subparts B and C), and Nonintegrated-Fine Papers (Subpart R); and testing and reporting for the acid, base/neutral, and pesticide fractions in the following subcategories: Fine Bleached Kraft (Subpart I), Dissolving Sulfite Pulp (Subpart K), Groundwood-Fine Papers (Subpart O), Market Bleached Kraft (Subpart G), Tissue from Wastepaper (Subpart T), and Nonintegrated-Tissue Papers (Subpart S).

5. Testing and reporting for the base/neutral fraction in the Once-Through Cooling Water, Fly Ash and Bottom Ash Transport Water process wastestreams of the Steam Electric Power Plant industrial category. This revision continues these suspensions. "See Note 1"]

Editorial Note: The words "This revision" refers to the document published at 48 FR 14153, April 1, 1983.

For the duration of the suspensions, therefore, Table 1 effectively reads:

Table 1. Testing Requirements for Organic Toxic Pollutants by Industry Category
GC/MS Fraction⁽¹⁾
Industrial Category	Volatile	Acid	Base/Neutral	Pesticides
Adhesives and Sealants	*	*	*
Aluminum Forming	*	*	*
Auto and Other Laundries	*	*	*	*
Battery Manufacturing	*	*
Coal Mining
Coil Coating	*	*	*
Copper Forming	*	*	*
Electric and Electronic Components	*	*	*	*
Electroplating	*	*	*
Explosives Manufacturing	*	*
Foundries	*	*	*
Gum and Wood (All Subparts except D and F)	*	*
Subpart D- tall oil rosin	*	*	*
Subpart F-rosin-based derivatives	*	*	*
Inorganic Chemicals Manufacturing	*	*	*
Iron and Steel Manufacturing	*	*	*
Leather Tanning and Finishing	*	*	*
Mechanical Products and Manufacturing	*	*	*
Nonferrous Metal Manufacturing	*	*	*	*
Ore Mining (Applies to the base and precious metals/Subpart B)	*
Organic Chemicals Manufacturing	*	*	*	*
Paint and Ink Formulation	*	*	*
Pesticides	*	*	*	*
Petroleum Refining	*
Pharmaceutical Preparations	*	*	*
Photographic Equipment and Supplies	*	*	*
Plastic and Synthetic Materials Manufacturing	*	*	*	*
Plastic Processing	*
Porcelain Enameling
Printing and Publishing	*	*	*	*
Pulp and Paper Mills (See Table 1.A below)
Rubber Processing	*	*	*
Soap and Detergent Manufacturing	*	*	*
Steam Electric Power Plants	*	*
Textile Mills (Subpart C-Griege Mills are exempt from this table)	*	*	*
Timber Products Processing	*	*	*	*

(1) The pollutants in each fraction are listed in Item V-C in the NPDES permit application.

*Testing required.

Table 1.A Pulp and Paperboard Mills - Exceptions
GC/MS Fraction⁽¹⁾
40 CFR Part 430 Subpart	Volatile	Acid	Base/Neutral	Pesticide
A	[DAGGER]	*	[DAGGER]	*
B	[DAGGER]	*	[DAGGER]	[DAGGER]
C	[DAGGER]	*	[DAGGER]	[DAGGER]
D	[DAGGER]	*	[DAGGER]	[DAGGER]
E	*	*	[DAGGER]	*
F	*	*	[DAGGER]	[DAGGER]
G	*	*	[DAGGER]	[DAGGER]
H	*	*	[DAGGER]	[DAGGER]
I	*	*	[DAGGER]	[DAGGER]
J	*	*	*	[DAGGER]
K	*	*	[DAGGER]	[DAGGER]
L	*	*	[DAGGER]	[DAGGER]
M	*	*	[DAGGER]	[DAGGER]
N	*	*	[DAGGER]	[DAGGER]
O	*	*	[DAGGER]	[DAGGER]
P	*	*	[DAGGER]	[DAGGER]
Q	*	*	[DAGGER]	*
R	[DAGGER]	*	[DAGGER]	[DAGGER]
S	*	*	[DAGGER]	*
T	*	*	[DAGGER]	*
U	*	*	*	[DAGGER]

(1) The pollutants in each fraction are listed in Item V-C in the NPDES permit application.

*Testing required.

[DAGGER] Do not test unless "reason to believe" it is discharged.

La. Admin. Code tit. 33, § IX-7107

Promulgated by the Department of Environmental Quality, Office of Water Resources, LR 21:945 (September 1995), repromulgated by the Office of Environmental Assessment, Environmental Planning Division, LR 30:233 (February 2004), amended by the Office of the Secretary, Legal Affairs Division, LR 32:1852 (October 2006).

AUTHORITY NOTE: Promulgated in accordance with R.S. 30:2001 et seq., and in particular Section 2074(B)(3) and (B)(4)