Ex Parte Chandra et alDownload PDFPatent Trial and Appeal BoardJun 6, 201813165216 (P.T.A.B. Jun. 6, 2018) Copy Citation UNITED STA TES p A TENT AND TRADEMARK OFFICE APPLICATION NO. FILING DATE 13/165,216 06/21/2011 49267 7590 06/08/2018 TUTUNJIAN & BITETTO, P.C. 401 Broadhollow Road, Suite 402 Melville, NY 11747 FIRST NAMED INVENTOR BHUPESH CHANDRA UNITED STATES DEPARTMENT OF COMMERCE United States Patent and Trademark Office Address: COMMISSIONER FOR PATENTS P.O. Box 1450 Alexandria, Virginia 22313-1450 www .uspto.gov ATTORNEY DOCKET NO. YOR920110191US1 (163-411) CONFIRMATION NO. 3408 EXAMINER BARTON, JEFFREY THOMAS ART UNIT PAPER NUMBER 1726 NOTIFICATION DATE DELIVERY MODE 06/08/2018 ELECTRONIC Please find below and/or attached an Office communication concerning this application or proceeding. The time period for reply, if any, is set in the attached communication. Notice of the Office communication was sent electronically on above-indicated "Notification Date" to the following e-mail address( es): docketing@tb-iplaw.com PTOL-90A (Rev. 04/07) UNITED STATES PATENT AND TRADEMARK OFFICE BEFORE THE PATENT TRIAL AND APPEAL BOARD Ex parte BHUPESH CHANDRA, AUGUSTIN J. HONG, JEEHW AN KIM, DEVENDRA K. SADANA, and GEORGE S. TULEVSKI Appeal2017-006053 Application 13/165 ,216 Technology Center 1700 Before LINDA M. GAUDETTE, JAMES C. HOUSEL, and CHRISTOPHER C. KENNEDY, Administrative Patent Judges. HOUSEL, Administrative Patent Judge. DECISION ON APPEAL 1 Pursuant to 35 U.S.C. § 134(a), Appellants2 appeal from the Examiner's decision rejecting claims 1, 3---6, 8, 11, 13, 14, 16-18, 20, 22, and 23. We have jurisdiction over the appeal under 35 U.S.C. § 6(b ). 1 Our decision refers to the Specification (Spec.) filed June 21, 2011, the Examiner's Final Office Action (Final Act.) dated February 24, 2016, Appellants' Appeal Brief (Appeal Br.) filed July 25, 2016, the Examiner's Answer (Ans.) dated January 6, 2017, and Appellants' Reply Brief (Reply Br.) filed March 6, 2017. 2 According to Appellants, the real party in interest is International Business Machines Corporation. Appeal Br. 4. Appeal2017-006053 Application 13/165,216 We AFFIRM. STATEMENT OF THE CASE The invention relates to photovoltaic devices having improved performance by reducing barriers for carbon-based electrodes. Spec. i-f 2. Appellants disclose that a Schottky barrier exists between the p-type (p- doped) layer of a solar cell stack and the transparent conductive thin film or transparent conductive oxide (TCO). Id. i-f 7. Appellants explain that "[t]he Schottky barrier is a potential barrier formed at a metal-semiconductor junction which has rectifying characteristics like a diode." Id. Claim 1, reproduced below from the Claims Appendix to the Appeal Brief, is illustrative of the subject matter on appeal. 1. A photovoltaic device, comprising: a photovoltaic stack having an N-doped layer, a P-doped layer of a material selected from the group consisting of amorphous silicon, amorphous hydrogenated silicon and a combination thereof, and an intrinsic layer; and a transparent electrode formed on the photovoltaic stack and including a carbon nanotube layer and a high work function metal layer, the high work function metal layer being gold nanodots having a size between 0.1 nm to and 20 nm, which is disposed at an interface between the carbon nanotube layer and the P-doped layer such that the high work function metal layer forms a reduced barrier contact and is light transmissive. Independent claim 11 recites a photovoltaic device substantially similar to claim 1, except for the material of the P-doped layer and further includes a reflective metal substrate disposed in contact with the N-doped layer. Independent claim 20 recites a method of forming a photovoltaic device substantially similar to claim 1. 2 Appeal2017-006053 Application 13/165,216 REJECTIONS The Examiner maintains, and Appellants request our review of, the following grounds of rejection under 35 U.S.C. § 103(a): 1. Claims 1 and 3---6 as unpatentable over Kim 3 in view of Tanaka· 4 ' 2. Claims 11, 13, 14, 17, and 18 as unpatentable over Kim in view of Tanaka and Zhu; 5 3. Claims 1, 3---6, 20, 22, and 23 as unpatentable over Hamakawa6 in view of Tanaka and Bemede; 7 4. Claims 4 and 23 as unpatentable over Hamakawa in view of Tanaka and Bemede, further in view ofYang; 8 5. Claims 11, 13, 14, 17, and 18 as unpatentable over Hamakawa in view of Tanaka, Zhu, and Bemede; 6. Claim 14 as unpatentable over Hamakawa in view of Tanaka, Zhu, and Bemede, further in view of Yang; 3 Jeehwan Kim, et al., The Role of High Work-Function Metallic Nanodots on the Peiformance of a-Si:H Solar Cells: Offering Ohmic Contact to Light Trapping, 4 ACSNANO 12, 7331-7336 (2010). 4 Tanaka et al., US 2006/0213547 Al, published September 28, 2006. 5 Hongwei Zhu et al., Applications of Carbon Materials in Photovoltaic Solar Cells, SOLAR ENERGY MATERIALS & SOLAR CELLS 93, 1461-1470 (2009). 6 Hamakawa et al., US 4,450,316, issued May 22, 1984. 7 J.C. Bemede et al., Improvement of Organic Solar Cell Performances Using a Zinc Oxide Anode Coated by an Ultrathin Metallic Layer, APPLIED PHYSICS LETTERS 92, 083304 (2008). 8 Yang et al., US 4,379,943, issued April 12, 1983. 3 Appeal2017-006053 Application 13/165,216 7. Claim 8 as unpatentable over Kim in view of Tanaka or Hamakawa in view of Tanaka and Bemede, further in view ofHanna9 and Nakamoto· 10 ' 8. Claim 16 as unpatentable over Kim in view of Tanaka and Zhu or Hamakawa in view of Tanaka, Zhu, and Bemede, further in view of Hanna and Yu. 11 ANALYSIS Rejection 1 The Examiner rejects claims 1 and 3---6 under 35 U.S.C. § 103(a) as unpatentable over Kim in view of Tanaka. Appellants argue the claims in this rejection as a group, focused on the limitations of claim 1 only. Claims 3---6 stand or fall with claim 1. The Examiner finds Kim, Figure 3a, discloses a silicon solar cell comprising a PIN photovoltaic junction device having a P-doped layer, an intrinsic layer, and an N-doped layer and made of hydrogenated amorphous silicon, and a transparent ZnO:Al electrode with a high work-function gold nanodot metal layer formed on the P-doped layer. Ans. 3--4. The Examiner finds Kim's gold nanodot layer is located at the interface between the transparent electrode and the P-doped layer, thereby forming a reduced barrier contact, and is light transmissive, with a thickness of 0.5 nm. Id. at 4. 9 Hanna et al., US 2014/0081028 Al, published March 20, 2014. 10 Nakamoto et al., US 6,417,606 Bl, issued July 9, 2002. 11 Young-Jun Yu et al., Tuning the Graphene Work Function by Electric Field Effect, 9 NANO LETTERS 10, 3430-3434 (2009). 4 Appeal2017-006053 Application 13/165,216 The Examiner acknowledges that Kim does not teach that the transparent electrode includes a carbon-based layer. Id. The Examiner relies on Tanaka for this feature, finding Tanaka discloses various carbon material layers, including carbon, carbon nanotubes, and fullerenes, that are interchangeable with metal oxide or transparent conductive oxide (TCO) for use as an electrode to the hydrogenated amorphous silicon P-doped layer in a PIN photovoltaic device. Ans. 5. In addition, the Examiner finds Tanaka teaches the transparent electrode can be formed of carbon nanotubes, TCO, metal layers, and combinations of two or more of these materials. Id. The Examiner concludes that it would have been obvious to modify the Kim device by forming the transparent electrode of carbon nanotubes in place of the TCO material because Tanaka teaches these materials are suitable alternatives to each other as the transparent electrode for the P-doped layer in a PIN photovoltaic device such as Kim's device and also that carbon and TCO materials are usable with metal in the electrode. Id. (citing In re Leshin, 277 F.2d 197 (CCPA 1960) and MPEP § 2144.07). Appellants note that none of the applied prior art references individually discloses a combination of a carbon nanotube layer and a high work-function metal layer of gold nanodots as an electrode to a doped photovoltaic cell. Appeal Br. 13. However, this fact is not of particular significance since the rejection is based on the obviousness of a combination of the teachings of the references. See In re Keller, 642 F.2d 413, 426 (CCP A 1981) ("[O]ne cannot show non-obviousness by attacking references individually where, as here, the rejections are based on combinations of references."). In addition, the Examiner acknowledges that Kim fails to 5 Appeal2017-006053 Application 13/165,216 teach the carbon nanotube layer, but finds that Kim otherwise teaches the remaining structure and materials of claim 1. In this regard, Appellants contend that Kim is "far removed" from Appellants' claimed invention because Kim's electrode does not include a carbon-based layer and, in particular, a carbon nanotube layer. Appeal Br. 14; Reply Br. 8. However, the fact that Kim does not include a carbon nanotube layer merely establishes that Kim does not anticipate the invention of claim 1, but does not establish that Kim is far removed therefrom. Indeed, as the Examiner finds, the only feature from claim 1 that is missing from Kim is the use of a carbon nanotube layer adjoining the gold nanodot layer to form the transparent electrode for the P-doped layer of Kim's PIN photovoltaic stack. Appellants further argue that the Specification, paragraphs 34--35, and Figures 2 and 3 illustrate how the combination of a carbon-based layer and a high work-function metal layer unexpectedly increased the performance of the solar cell relative to the prior art. Appeal Br. 14. According to Appellants, this evidence illustrates the criticality of including both the carbon-based layer and the high work-function metal layer to provide a solar cell electrode that does not suffer from a Schottky barrier problem or Fermi level pinning. Id. In particular, Appellants explain that Figure 2 and paragraph 34 demonstrate that when carbon is disposed on a P-doped a-Si:H layer of a PIN stack, the Schottky barrier becomes severe due to Fermi level pinning at the carbon/P-doped layer interface. Id. at 15. As such, Appellants urge that these cells cannot properly function as solar cells, and 6 Appeal2017-006053 Application 13/165,216 they would not be considered as an alternative to a TCO. Id. 15-16; see also Reply Br. 7-8. On the other hand, Appellants explain that Figure 3 and paragraph 3 5 demonstrate that PIN solar cells having a high work-function metal layer between the carbon-based layer and the P-doped a-Si:H layer performed comparably or better than cells having only a TCO material electrode. Appeal Br. 19. Appellants assert that none of the prior art recognize the critical nature of the high work-function metal layer to providing the performance enhancements needed to render carbon-based electrodes suitable for solar cells. Id. The burden of establishing that unexpected results support a conclusion of nonobviousness rests with Appellants. In re Huang, 100 F.3d 135, 139 (Fed. Cir. 1996). "[W]hen unexpected results are used as evidence of nonobviousness, the results must be shown to be unexpected compared with the closest prior art." In re Baxter Travenol Labs., 952 F.2d 388, 392 (Fed. Cir. 1991 ). "[I]t is not enough to show that results are obtained which differ from those obtained in the prior art: that difference must be shown to be an unexpected difference." See In re Klosak, 455 F.2d 1077, 1080 ( CCP A 1972 ). Additionally, "it is well settled that unexpected results must be established by factual evidence. 'Mere argument or conclusory statements in the specification does not suffice."' See In re Geisler, 116 F.3d 1465, 1470 (Fed. Cir. 1997) (quoting In re De Blauwe, 736 F.2d 699, 705 (Fed. Cir. 1994)); see also In re Pearson, 494 F.2d 1399, 1405 (CCPA 1974) ("Attorney's argument in a brief cannot take the place of evidence."). Here, the Examiner finds that because Kim teaches the benefit of an ultrathin work-function metal layer at the interface of the transparent 7 Appeal2017-006053 Application 13/165,216 electrode and that this layer can alleviate the increasing Schottky barrier produced when increasing amounts of carbon are added to the P-doped layer, the improved results shown in Appellants' disclosure would have been expected to the person of ordinary skill in this art. Ans. 37-38. As the Examiner finds, Kim shows that the Schottky barrier is reduced and current density of high C content in the p-type layer improves substantially when combined with a 0.5nm gold nanodot layer. Id. at 38; Kim, Figs. 2a and 2b. This reduction in the Schottky barrier and improvement in current density is substantially the same as shown in Appellants' Figures 2 and 3. Accordingly, the Examiner's determination that reduction in the Schottky barrier height and improvement in current density would not have been unexpected to those skilled in the art is supported by Kim's disclosure. The Examiner further finds that Appellants' evidence and arguments are not commensurate with the teachings of the applied prior art, which teach bilayer electrode structures including a high work-function metal layer between a TCO layer and the P-doped layer of a PIN stack. Ans. 37. As the Examiner finds, none of the examples in Figure 2 contains a combination of a TCO and a metal layer as the electrode as taught by Kim. Id. Although Appellants disagree (Reply Br. 7), it is clear that each of the Figure 2 examples uses only a single electrode material without any intervening metal layer. Furthermore, the Examiner notes that Appellants' evidence does not establish that carbon-based electrodes are inoperable, but merely that they are inferior to a TCO electrode. Id. Kim teaches similar results to Appellants' Figure 2, i.e., higher C content p-type layers have reduced efficiencies, but are otherwise still operable devices. Kim, Figs. 1 and 2. In light of these findings, we agree with the Examiner that Appellants have not 8 Appeal2017-006053 Application 13/165,216 established that the use of carbon-based electrodes, including a carbon nanotube layer, in PIN stack solar cells would have been inoperable. We further note that Appellants fail to direct our attention to any evidence supporting a conclusion that Appellants' results would have been unexpected to one of ordinary skill in the art. The only mention that the results are unexpected appears in Appellants' arguments, not in their Specification or other evidentiary documentation. Geisler, 116 F.3d at 1470. Therefore, Appellants have not carried their burden of establishing unexpected results in support of a conclusion of nonobviousness. Appellants also argue that Kim leads away from an increase in carbon content within the solar cell. Appeal Br. 16 (citing Kim, p. 7331, 2nd para. and p. 7335, 1st para.). However, Kim also teaches that a higher carbon content in the window layer is desirable because it increases its band gap. Kim, p. 7331, 2nd para. "[A] given course of action often has simultaneous advantages and disadvantages, and this does not necessarily obviate motivation to combine." Medichem, S.A. v. Rolabo, S.L., 437 F.3d 1157, 1165 (Fed. Cir. 2006). This is especially applicable here because Kim further teaches mitigation of the recognized disadvantage of increasing Schottky barrier height for increased carbon content by the inclusion of the intervening gold nanodot layer. Finally, Appellants argue that the Examiner's reliance on Tanaka is in error because Appellants have demonstrated that carbon electrodes and ZnO based electrodes are not equally suitable for use in solar cells. Appeal Br. 17. Appellants note that Tanaka fails to teach or suggest a high work- function metal layer. Id. at 20. Appellants assert they have shown that carbon-based electrodes used as electrodes in solar cell results in inoperable 9 Appeal2017-006053 Application 13/165,216 performance when compared to a ZnO electrode when directly contacting the doped semiconductor layer of the solar cell. Id. at 17. Appellants urge that, prior to their discovery, carbon-based electrodes and ZnO electrodes were not interchangeable materials suitable for electrodes in solar cells. Id. at 18. Therefore, Appellants reassert that the suitability of carbon electrodes in solar cells when combined with a high work-function metal is an unexpected result. Id. at 18-19. Initially, we note that the Examiner relies on a combination of the teachings of Kim and Tanaka in support of the conclusion of obviousness. Therefore, it is not persuasive of reversible error in this combination that Tanaka fails to teach a high work-function metal layer combined with a carbon-based electrode, as the Examiner does not rely on Tanaka for this teaching. Instead, the Examiner relies on Tanaka for its teaching that various materials are known alternatives for use alone or in combination as a transparent electrode in a solar cell. Specifically, Tanaka teaches any of a number of known materials may be used as the transparent electrode of a solar cell including various metal oxides or TCOs, various metals including gold, and various carbon materials including carbon, carbon nanotubes, and fullerenes. Tanaka i-f 52. Tanaka further teaches one or a combination of these materials may be used. Id. i-f 53. As explained above, although Appellants contend they have demonstrated that carbon-based electrodes are inoperable, the evidence suggests that carbon-based electrodes may be somewhat inferior to TCO electrodes in efficiency, but have other advantages, and are otherwise operable. When taken with Kim's teaching that an intervening gold nanodot layer reduces the Schottky barrier height attributed to carbon, the ordinary artisan would have had a reasonable 10 Appeal2017-006053 Application 13/165,216 expectation of success substituting a known carbon-based electrode material for Kim's TCO electrode as Tanaka teaches these are known alternatives for the same purpose and carbon can improve the band gap of the solar cell. Accordingly, in view of the Examiner's findings and reasoning set forth in the Answer, as well as the reasons set forth above, weighed against Appellants' arguments and evidence, we determine that a preponderance of the evidence supports the Examiner's conclusion of obviousness of claims 1 and 3-6. Re} ection 2: The Examiner rejects claims 11, 13, 14, 17, and 18 as unpatentable over Kim in view of Tanaka and Zhu. Appellants argue the claims in this rejection as a group, focused on the limitations of claim 11 only. Claims 13, 14, 17, and 18 stand or fall with claim 11. Claim 11 is reproduced below from the Claims Appendix to the Appeal Brief. 11. A photovoltaic device, comprising: a photovoltaic stack having a P-type layer, an intrinsic layer and an N-type layer; a transparent electrode formed on the P-type layer of the photovoltaic stack, the transparent electrode including a conductive carbon based layer of graphene and a high work function metal layer, the high work function metal layer being gold nanodots having a size between 0.1 nm to and 20 nm, which is disposed at an interface between the carbon based layer and the P-type layer such that the high work function metal layer forms a reduced barrier contact and is light transmissive; and a reflective metal substrate disposed in contact with the N-type layer. 11 Appeal2017-006053 Application 13/165,216 Claim 11 recites a photovoltaic device similar to the photovoltaic device or claim 1, and includes the further limitation that the carbon-based electrode is graphene and a recitation of a reflective metal substrate disposed in contact with the N-type layer. The Examiner finds Kim discloses, inter alia, a silver metal layer disposed in contact with the N-type layer. Ans. 8. The Examiner finds that the silver electrode is inherently reflective. Id. Indeed, Appellants disclose that silver is a highly reflective metal. Spec. i-f 31. The Examiner further finds Zhu discloses several carbon materials suitable for use as an electrode material in solar cells, specifically teaching graphene as a highly transparent and conductive material similar to carbon nanotubes as a replacement for metal oxide electrodes in solar cells. Ans. 10. The Examiner, therefore, concludes that it would have been obvious to substitute graphene as the material for Kim's electrode because Tanaka teaches carbon electrodes are known alternatives to Kim's TCO electrode and Zhu teaches that graphene is a known carbon material for use as an electrode in solar cells. Id. (citing Leshin, 277 F.2d 197, and MPEP § 2144.07 (selection of a known material based upon its suitability for the intended use is within the level of ordinary skill in the art). Appellants repeat the same arguments against this rejection as raised against Rejection 1. For the same reasons given above, we are not persuaded of reversible error in the Examiner's conclusion of obviousness. Accordingly, we likewise affirm the Examiner's§ 103 rejection of claims 11, 13, 14, 17, and 18 over the combination of Kim, Tanaka, and Zhu. Rejection 5 12 Appeal2017-006053 Application 13/165,216 The Examiner rejects claims 11, 13, 14, 17, and 18 as unpatentable over Hamakawa in view of Tanaka, Zhu, and Bemede. Appellants argue the claims in this rejection as a group, focused on the limitations of claim 11 only. Claims 13, 14, 1 7, and 18 stand or fall with claim 11. The Examiner finds Hamakawa, Figure 1 a, discloses a photovoltaic device comprising a PIN photovoltaic junction device having P-doped layer 3, intrinsic layer 4, and N-doped layer 5, TCO electrode 2 with an intervening thin metal layer formed on the P-doped layer, and an aluminum electrode on the N-doped layer. Ans. 11-12, 16. The Examiner acknowledges that Hamakawa does not teach that the transparent electrode includes a graphene layer, that the thin metal layer is a high work-function material, or that the electrode on the N-doped layer is reflective. Id. at 12, 15. However, the Examiner finds that Hamakawa's electrode on the N- doped layer is inherently reflective because aluminum is a metal. Id. at 16. The Examiner also finds Tanaka discloses various carbon material layers, including carbon, carbon nanotubes, and fullerenes, that are interchangeable with metal oxide or transparent conductive oxide (TCO) for use as an electrode to the P-doped layer in a PIN photovoltaic device. Ans. 12. In addition, the Examiner finds Tanaka teaches the transparent electrode can be formed of carbon nanotubes, TCO, metal layers (including gold), and combinations of two or more of these materials. Id. at 12, 14. The Examiner further finds Zhu discloses several carbon materials suitable for use as an electrode material in solar cells, specifically teaching graphene as a highly transparent and conductive material similar to carbon nanotubes as a replacement for metal oxide electrodes in solar cells. Id. at 12-13. The Examiner, therefore, concludes that it would have been obvious to substitute 13 Appeal2017-006053 Application 13/165,216 graphene and gold as the materials for Hamakawa's electrode and intervening thin metal layer because Tanaka teaches carbon and gold electrodes are known alternatives to Hamakawa's TCO electrode and Zhu teaches that graphene is a known carbon material for use as an electrode in solar cells. Id. at 13-14 (citing Leshin, 277 F.2d 197, and MPEP § 2144.07). The Examiner further finds that Hamakawa, as modified in view of Tanaka and Zhu, fails to teach that the intervening thin gold layer is formed of a discontinuous layer of nanodots. Ans. 17. The Examiner finds Bemede discloses an ultrathin metal layer disposed between the transparent electrode and the photovoltaic layers of a solar cell, similar to Hamakawa, whose optimal thickness is 0.5 nm± 0.2 nm to allow for high optical transmittance, while reducing the interface barrier and increasing charge transport efficiency. Id. The Examiner finds that Bemede teaches this thin gold layer is discontinuous and forms nanodots. Id. Therefore, the Examiner concludes that it would have been obvious to optimize the thickness of the intervening gold layer in Hamakawa, as modified, such that the layer is discontinuous and forms nanodots in order to increase optical transmittance, while reducing the interface barrier and increasing the charge transport efficiency as taught by Bemede. Id. at 18. To the extent that Appellants repeat substantially the same arguments against this rejection as raised against Rejection 1, those arguments are not persuasive of reversible error for the same reasons given above. Appellants additionally assert that Bemede discloses organic photovoltaic cells, whereas the claimed photovoltaic cells are inorganic. Appeal Br. 31. However, this alleged distinction is not germane to claim 11 which does not recite any material limitation for the photovoltaic PIN stack. Further, although 14 Appeal2017-006053 Application 13/165,216 Appellants argue that Bemede fails to teach carbon-based electrodes, and fails to teach the photovoltaic device of claim 11 (id.), this argument fails to address the rejection at issue, particularly because Bemede was not applied as teaching carbon-based electrodes or as an anticipatory teaching of the device of claim 11. Accordingly, we likewise affirm the Examiner's§ 103 rejection of claim 11 over the combination of Hamakawa, Tanaka, Zhu, and Bemede. Rejection 3 The Examiner rejects claims 1, 3---6, 20, 22, and 23 as unpatentable over Hamakawa in view of Tanaka and Bemede. Appellants argue the claims in this rejection as a group, focused on the limitations of claim 1 only. Claims 3-6, 20, 22, and 23 stand or fall with claim 1. Appellants repeat the same arguments against this rejection as raised against Rejection 1. For the same reasons given above, we are not persuaded of reversible error in the Examiner's conclusion of obviousness. Accordingly, we likewise affirm the Examiner's§ 103 rejection of claim 1 over the combination of Hamakawa, Tanaka, and Bemede. Re} ections 4 and 6 In addition to the rejection of claims 4 and 23 as unpatentable over the combination of Hamakawa, Tanaka, and Bemede (rejection 3), and the rejection of claim 14 over the combination of Hamakawa, Tanaka, Bemede, and Zhu (rejection 5), the Examiner rejects these claims over the same combinations of references, further in view of Yang. Appellants rely on the same arguments presented in support of patentability of the claims subject to 15 Appeal2017-006053 Application 13/165,216 rejections 3 and 5, adding only that Yang fails to remedy the deficiencies in the prior art applied in those rejections. Appeal Br. 33. However, for the reasons given above, we are not persuaded of any deficiencies in rejections 3 and 5. Accordingly, we affirm the Examiner's rejections of claims 4 and 23, and claim 14, as unpatentable over the combination of references relied upon in rejections 4 and 6, respectively. Rejection 7 The Examiner rejects claim 8 as unpatentable over Kim in view of Tanaka, or Hamakawa in view of Tanaka and Bemede, further in view of Hanna and Nakamoto. Appellants merely assert that Hanna does not disclose the use of carbon-based electrodes in solar cells and Nakamoto does not disclose photovoltaic devices. Appeal Br. 34. However, this "separate" argument amounts to no more than assertions unrelated to the basis upon which the Examiner relied on these references. Our reviewing court has long held that such "argument" does not merit separate consideration. See, e.g., In re Lovin, 652 F.3d 1349, 1357 (Fed. Cir. 2011). Accordingly, we affirm the Examiner's rejection of claim 8. Rejection 8 The Examiner rejects claim 16 as unpatentable over Kim in view of Tanaka and Zhu or Hamakawa in view of Tanaka, Zhu, and Bemede, further in view of Hanna and Yu. Appellants merely assert that Hanna and Yu do not disclose the use of carbon-based electrodes in solar cells. Appeal Br. 34. However, this "separate" argument amounts to no more than assertions 16 Appeal2017-006053 Application 13/165,216 unrelated to the basis upon which the Examiner relied on these references. This "argument" does not merit separate consideration. See Lovin, 652 F.3d at 1357. Accordingly, we affirm the Examiner's rejection of claim 16. DECISION Upon consideration of the record, and for the reasons given above and in the Examiner's Answer, the decision of the Examiner rejecting claims 1, 3---6, 8, 11, 13, 14, 16-18, 20, 22 and 23 under 35 U.S.C. § 103(a) as unpatentable is affirmed. No time period for taking any subsequent action in connection with this appeal maybe extended under 37 C.F.R. § 1.136(a)(l). AFFIRMED 17 Copy with citationCopy as parenthetical citation